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Prevention of Galvanic corrosion

One type of corrosion that is often overlooked in the moldmaking industry is galvanic corrosion. Sometimes it is identified wrongly as electrolysis. Galvanic corrosion refers to the damage induced when two dissimilar metals are coupled in a corrosive electrolyte. When this occurs, the less noble (less able to resist this type of corrosion) of the metals in the reaction becomes the anode (positive) and corrodes more quickly than it would by itself, whereas the more noble metal becomes the cathode (negative) and corrodes more slowly than it would alone.

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Prevention of Intergranular Corrosion

Sometimes Intergranular corrosion is also called intercrystalline corrosion or interdendritic corrosion. In the presence of tensile stress, cracking may occur along grain boundaries.This type of corrosion is frequently called interranular stress corrosion cracking (IGSCC) or intergranular corrosion cracking.

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Prevention of crevice corrosion

Crevice Corrosion refers to the localized attack on a metal surface at, or immediately adjacent to, the gap or crevice between two joining surfaces. The gap or crevice can be formed between two metals or a metal and non-metallic material. Outside the gap or without the gap, both metals are resistant to corrosion. Crevice corrosion is not unique to stainless steels. It can occur in other alloys including those of aluminium, titanium and copper.

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Prevention of Rust

Rust is the common term for corroded steel or iron. It is very common compound, iron oxide. Iron oxide, the chemical Fe2O3, is common because iron combines very readily with oxygen. It is so readily that pure iron is only rarely found in nature. The reddish oxide produced is caused by oxygen and moisture.

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Pitting

Pitting is used to describe the formation of small pits on the surface of a metal or alloy. Pitting is suspected to occur in much the same way crevice corrosion does, but on a flat surface.  A small imperfection in the metal is thought to begin the process, then a "snowball" effect takes place. Pitting can go on undetected for extended periods of time, until a failure occurs. Stainless steel to a chloride containing stream such as seawater, Pitting would overrun the stainless steel in a matter of weeks due to it's very poor resistance to chlorides, which are notorious for their ability to initiate pitting corrosion.

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Sacrificial Anodes

A cathodic protection system is a corrosion cell in which the structure to be protected is the cathode. Sacrificial or galvanic systems are corrosion cells of the differential metal type. The earliest experiments on cathodic protection were performed with zinc anodes that were electrically connected to copper plates immersed in seawater. From galvanic series, an arrangement would produce a cathode (copper) and an anode (zinc). In the large galvanic cell so formed, the zinc cylinder corroded away in a manner to protect the copper substrate. This method of cathodic protection can be used with other combination of metals providing the necessary current to the metal to be protected.

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Galvanic Corrosion with example of Couple between Steel and Brass

Galvanic corrosion refers to corrosion damage induced when two dissimilar materials are coupled in a corrosive electrolyte.

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Impressed Current Cathodic Protection

 (ICCP)
Cathodic protection can be applied if the metal to be protected is coupled to the negative pole of a direct current source (schematic), while the positive pole is coupled to an auxiliary anode. Since the driving voltage is provided by the DC source there is no need for the anode to be more active than the structure to be protected.

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Cathodic protection for cars

Electronic rust prevention for cars

The basic principle of cathodic protection  is very simple. A metal dissolution is reduced through the application of a cathodic current. Cathodic protection is often applied to coated structures, with the coating providing the primary form of corrosion protection. The CP current requirements tend to be excessive for uncoated systems.

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Corrosion Pit Shapes

Pitting corrosion can produce pits with their mouth open (uncovered) or covered with a semi-permeable membrane of corrosion products.

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Sewer explosion due to corrosion
An example of corrosion damages with shared responsibilities was the sewer explosion that killed 215 people in Guadalajara, Mexico, in April 1992. Besides the fatalities, the series of blasts damaged 1,600 buildings and injured 1,500 people.
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Rusting of iron

Explanation of the Rusting of Iron

When iron rusts a spontaneous redox reaction occurs, between the oxygen and iron. If water is added the rusting occurs more rapidly.

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Creep and Stress Rupture

High Temperature Failure Analysis

Creep occurs under load at high temperature.  Boilers, gas turbine engines, and ovens are some of the systems that have components that experience creep.  An understanding of high temperature materials behavior is beneficial in evaluating failures in these types of systems.

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Marine Corrosion
Marine corrosion includes the immersion of components in a seawater, equipment and piping that use seawater or brackish water, and corrosion in marine atmospheres.  Exposure of components can be continuous or intermittent.  Ships, marinas, pipelines, offshore structures, desalination plants, and heat exchangers are some examples of systems that experience marine corrosion.
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Casting Failure

Castings

Several factors effect the quality of metal castings.

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