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Rusted-out cars and bathroom stains Print E-mail


If you have an older car, the corrosion occur at the joints between body parts and under paint films; and once corrosion starts, it tends to feed on itself.

One reason for this is that one of the products of the O2 reduction reaction is hydroxide ion. The high pH produced in these cathodic regions tends to destroy the protective oxide film, and may even soften or weaken paint films, so that these sites can become anodic. The greater supply of electrons promotes more intense cathodic action, which spawns even more anodic sites, and so on.

A very common cause of corrosion is having two dissimilar metals in contact, as might occur near a fastener or at a weld joint. Moisture collects at the junction point, acting as an electrolyte and forming a cell in which the two metals serve as electrodes. Moisture and conductive salts on the outside surfaces provide an external conductive path, effectively short-circuiting the cell and producing very rapid corrosion; this is why cars rust out so quickly in places where salt is placed on roads to melt ice.

Dissimilar-metal corrosion can occur even if the two metals are not initially in direct contact. For example, in homes where copper tubing is used for plumbing, there is always a small amount of dissolved Cu2+ in the water. When this water encounters steel piping or a chrome-plated bathroom sink drain, the more-noble copper will plate out on the other metal, producing a new metals-in-contact corrosion cell. In the case of chrome bathroom sink fittings, this leads to the formation of Cr3+ salts which precipitate as greenish stains.

 
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