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Controlling corrosion in concrete structures to be built Print E-mail


Cover around reinforcement
The reinforced concrete structures are designed and built for a service life, which is defined by the designer and is controlled by the manufacturer. For this period of time, the structure should not be so deteriorated that it does not fulfill any more its functions.

The deterioration of reinforced concrete is mainly due to reinforcement corrosion and the mechanism of this deterioration is to be reminded.

Reinforcements corrode when they are in contact with a high amount of aggressive agents. This is the reason why, the prevention of reinforcement corrosion, in structures to be built, is obtained mainly by controlling the thickness and the quality of the concrete cover.

The design of traditional concrete, in particular its cement dosage and its water-cement content ratio, depends on the environment to which this material is exposed.

Chart 1- Requirements on concrete according to exposure classes,
according to standard ENV 1992.1.1 " Eurocode 2")
Environment---Environment class---Minimum cement dosage (kg/m3)---Minimum water-cement ratio
  • dry                                                         --- 1 --- 280 --- 0,65
  • wet (without freezing)                             ---2a --- 280 --- 0,60
  • wet (with freezing)                                  ---2b --- 280 --- 0,55
  • wet and freezing (with use of deicing salts)--- 3 ---  300--- 0,50
  • sailor without freezing)                             ---4a---  300 --- 0,55
  • sailor (with freezing)                                ---4b---  300  ---0,50
  • chemical (slightly aggressive)                    ---5a --- 280 ---0,55
  • chemical (fairly aggressive)                     --- 5b --- 300 --- 0,50
  • chemical (highly aggressive)                     --- 5c  ---300--- 0,45

In very particular cases, additives can be added in the freshly-mixed concrete to improve of its workability, its mechanical properties and more rarely its protective qualities.

The concrete cover thickness around reinforcement also depends on the environment aggressiveness. But, in addition to the requirements given by the designer, it is significant to consider the implementation (reinforcements positioning, concrete mixing, curing, etc.) to estimate the durability of a reinforced concrete really in place.

Reinforcement covers
When reinforced concrete structures are exposed to a very aggressive environment, an additional protection can be considered by cover steel. The two types of the most frequent covers on steel are organic coatings and metal coatings (hot-dip galvanising, etc). These protective coatings which must adhere to steel must also ensure good a bond between reinforcement and concrete.

Coatings on concrete
Protection against corrosion can also be to improve using a coating on concrete. The purpose of coatings on concrete are to prevent reinforcement corrosion, by ensuring a proofing either water, or with gases.

In details, membranes and coatings which are not subjected to a direct action of the atmosphere, in this case, the internal moisture of the underlying concrete varies little with time, coating systems applied on visible facings. Under these coatings, the internal moisture of the concrete can fluctuate. Water can evaporate from concrete or return there as a vapour. Gas flows (oxygen, carbon dioxide) can also cross these coatings.

The effectiveness of coatings is characterised on products or concrete substrate. As a rule, the test consists in measuring the fluid (liquid or gas) flux crossing a covered specimen.

A coating on concrete can be deteriorated by disbonding, blistering or formation of wrinkles (following chart 2).

Chart 2- Damage of the coatings applied to a concrete whose internal moisture fluctuates in the course of time
  • Origins            ---Conditions             ---Too bad
  • chemical attacks---Reactive components, etc.---Disbonding, Dissolution
  • capillary suction overpressure in concrete---adsorption of water, cement pores unsaturated with water---Disbonding, Blistering
  • solvent or vapour overpressure---Rise in temperature, cement pores unsaturated with water---Disbonding, Blistering
  • osmotic processes---semi-permeable membranes, coating components soluble in water---Disbonding, Blistering, Wrinkles
  • Fastening and internal stresses---temperature rise, differences in thermal expansions between coating and substrate---Disbonding, Wrinkles, Cracks

In practice, conventional life tests are carried out on coated concrete, to assess the performances of their protections. These tests often consist in putting specimens in a salt spray chamber and making them undergo various actions, such as temperature changes or ultraviolet rays.

Image of concrete corrosion 2

Impregnation with water proof products (sealant)
A water-proof product is a barrier against the penetration of liquid water, into concrete. It is called a surface product, when it is applied onto hardened concrete. A sealant and a water repellent have only an indirect action on reinforcement corrosion.
The choice of a water repellent to be applied, depends on many parameters concerning concrete (porosity, cleanliness, etc), the product and the local conditions for application (mainly, climatic conditions).
 
Impregnation with corrosion inhibitors
A corrosion inhibitor is a product which, once in contact with steel, protects it against corrosion. In the case of an existing structure, an inhibitor is applied by impregnating concrete surface and it migrates in concrete down to reinforcement. The penetration of an inhibitor depends on many factors related to the product type, to concrete properties, and to local conditions (climatic, etc.) for application. This is the reason why, it is recommended, for each case, to check that the amount of inhibitor is high enough at the reinforcement level.
Reference- http://www.concretecorrosion.net/ 
Standards, recommendations, guides
  • European standard EN 12696 " Cathodic protection of steel in concrete " (July 2000).
  • Draft standard prEN 14038-1 " Electrochemical re-alkalisation and chloride extraction for reinforced concrete. Part I : Re-alkalisation ".
 
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