| Pipeline Stress Corrosion Cracking (SCC) |
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corrosion doctors Over 98% of pipelines are buried. No matter how well these pipelines are designed, constructed and protected, once in place they are subjected to environmental abuse, external damage, coating disbondments, inherent mill defects, soil movements or instability and third party damage. In pipelines this occurs due to a combination of appropriate environment, stresses (absolute hoop and/or tensile, fluctuating stress) and material (steel type, amount of inclusions, surface roughness.) Environment is a critical causal factor in SCC. High-pH SCC failures of underground pipelines have occurred in a wide variety of soils, covering a range in color, texture, and pH. No single characteristic has been found to be common to all of the soil samples. Similarly, the compositions of the water extracts from the soils have not shown any more consistency than the physical descriptions of the soils. On several occasions, small quantities of electrolytes have been obtained from beneath disbonded coatings near locations where stress corrosion cracks were detected. The principle components of the electrolytes were carbonate and bicarbonate ions and it is now recognized that a concentrated carbonate-bicarbonate environment is responsible for this form of cracking. Much of this early research focused on the anions present in the soils and electrolytes. In addition to an appropriate coating failure, the local soil, temperature, water availability, and bacterial activity have a critical impact on SCC susceptibility. Coating types such as coal tar, asphalt and polyethylene tapes have demonstrated susceptibility to SCC. Fusion bonded epoxy hasn't shown susceptibility to SCC. Loading is the next most important parameter on SCC. Cyclic loading is considered a very important factor; or the crack tip strain rate defines the extent of corrosion or hydrogen ingress into the material. There has been no systematic effect of yield strength on SCC susceptibility. Certain types of ERW pipe have been found to be systematically susceptible to SCC. Non-metallic inclusions have also had limited correlation to SCC initiation. SCC propensityThere are two types of SCC normally found on pipelines, and known as high pH (9 to 13) and near-neutral pH SCC (5 to 7). The high pH SCC caused numerous failures in USA in the early 1960's and 1970's, whereas near-neutral pH SCC failures were recorded in Canada during the mid 1980's to early 1990's. The SCC failures have continued throughout the world including Australia, Russia, Saudi Arabia, South America and other parts of the world. High pH SCC Intergranular cracking mode generally represents high pH SCC. A thin oxide layer is formed in the concentrated carbonate-bicarbonate environment, which around the crack surfaces provides protection. However, due to changes in loading or cyclic loading there is crack tip strain resulting in breakage of oxide film. This results in crack extension due to corrosion. Because of such a stringent environmental requirement for SCC initiation, this is not as prevalent as the near-neutral pH SCC. This type of SCC has been primarily noted in gas transmission lines (temperature.) High pH SCC Integrity Management Strategy If SCC susceptible If SCC not found but still parameters indicate susceptibility. Near-neutral pH SCC A cyclical load is critical for crack initiation and growth. There are field data that indicate that with a decreasing stress ratio there is an increased propensity for cracking. Hydrogen is considered a key player in this SCC mechanism, where it reduces the cohesive strength at the crack tip. Attempts have been made to relate soil and drainage type with SCC susceptibility, however limited correlation's have been noted. There has been no correlation to a clear threshold for SCC initiation or growth. The morphology of the cracks are wide with evidence of substantial corrosion on the crack side wall. Near-neutral pH SCC management If SCC susceptible, and extent is not low – quantify life of the pipeline, utilizing fracture mechanics models and excavation data. If SCC susceptible, but the extent of SCC is very low. |
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